Many non-metallic materials are in general use. Their improved properties have resulted in their replacing conventional metals for many applications. The majority are organic, being produced either synthetically or from naturally occurring material. Ceramics are being increasingly considered for marine use particularly where galvanic corrosion is a problem.
Sintered alpha silicon carbide and other silicon-based ceramics have good strength properties and are inert in seawater. The general term 'plastic' is used to describe many of these non-metallic materials. Plastics are organic materials which can be moulded to shape under the action of heat or heat and pressure.
There are two main classes, thermoplastic and thermosetting, although some more modern plastics are strictly neither. Thermoplastic materials are softened by heat and can be formed to shape and then set by cooling, e.g. perspex, polyvinyl chloride (PVC) and nylon. Thermosetting materials are usually moulded in a heated state, undergo a chemical change on further heating and then set hard, for example, Bakelite, epoxy resins and polyesters.
Some general properties of plastic materials are good corrosion resistance, good electrical resistance and good thermal resistance; but they are unsuitable for high temperatures. To improve or alter properties, various additives or fillers are used, such as glass fibre for strength.
Asbestos fibre can improve heat resistance and mica is sometimes added to reduce electrical conductivity. Foamed plastics are formed by the liberation of gas from the actual material, which then expands to form a honeycomb-like structure.
Such materials have very good sound and heat-insulating properties. Many plastics can be foamed to give low-density materials with a variety of properties, for example, fire extinguishing. Some well-known nonmetallic materials are:
Asbestos
A mineral which will withstand very high temperatures and is unaffected by steam, petrol, paraffin, fuel oils and lubricants. It is used in many forms of jointing or gasket material and in various types of gland packing. It does however present a health hazard in some forms.
Cotton
A fibrous material of natural origin which is used as a backing material for rubber in rubber insertion jointing. It is also used in some types of gland packing material.
Glass-reinforced plastics (GRP)
A combination of thin fibres of glass in various forms which, when mixed with a resin, will cure (set) to produce a hard material which is strong and chemically inert. It has a variety of uses for general repairs.
Lignum
vitae A hardwood which is used for stern bearing lining. It can be lubricated by seawater but is subject to some swelling.
Nylon
A synthetic polymer which is chemically inert and resistant to erosion and impingement attack. It is used for orifice plates, valve seats and as a coating for saltwater pipes.
Polytetrafluorethylene (PTFE)
A fluoropolymer which is chemically inert and resistant to heat. It has a low coefficient of friction and is widely used as a bearing material. It can be used dry and is employed in sealed bearings. Impregnated with graphite, it is used as a filling material for glands and guide rings.
Polyvinylchloride (PVC)
A vinyl plastic which is chemically inert and used in rigid form for pipework, ducts, etc. In a plasticised form it is used for sheeting, cable covering and various mouldings.
Resin
Resins are hard, brittle substances which are insoluble in water. Strictly speaking, they are added to polymers before curing. The term 'resin' is often incorrectly used to mean any synthetic plastic. Epoxy resins are liquids which can be poured and cured at room temperature. The cured material is unaffected by oils and seawater. It is tough, solid and durable and is used as a chocking material for engines, winches, etc.
Rubber
A tree sap solidifies to form a rough, elastic material which is unaffected by water but is attacked by oils and steam. It is used as a jointing material for fresh and seawater pipes and also for water-lubricated bearings.
When combined with sulphur (vulcanized) it forms a hard material called 'ebonite' which is used for bucket rings (piston rings) in feed pumps. Synthetic rubbers such as neoprene and nitrile rubber are used where resistance to oil, mild chemicals or higher temperatures is required.
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